70615-33-7Relevant academic research and scientific papers
The Infrared spectrum, light-induced infrared linear dichroism and conformational analysis of phenyl azide in solid nitrogen at 12 K
Dunkin, Ian R.
, p. 649 - 656 (1986)
Phenyl azide (PhN3) and an isotopic mixture of Ph(14)N3 and Ph(15)N(14)N(14)N were isolated in N2 matrices at 12 K, and i.r. spectra in the range 4000-400 cm-1 were recorded.Photolysis of matrix-isolated PhN3 with plane-polarized light generate
Laser-Induced Fluorescence Spectrum of the Cyanocyclopentadienyl Radical. A Band System Long Attributed to Triplet Phenylnitrene
Cullin, David W.,Soundararajan, N.,Platz, Matthew S.,Miller, Terry A.
, p. 8890 - 8896 (1990)
The UV electronic spectrum long attributed to the triplet phenylnitrene intermediate has been reexamined.A variety of evidence strongly indicates that the true carrier of this spectrum is not phenylnitrene, but the cyanocyclopentadienyl radical.This evide
Flow synthesis of organic azides and the multistep synthesis of imines and amines using a new monolithic triphenylphosphine reagent
Smith, Catherine J.,Smith, Christopher D.,Nikbin, Nikzad,Ley, Steven V.,Baxendale, Ian R.
supporting information; experimental part, p. 1927 - 1937 (2011/04/21)
Here we describe general flow processes for the synthesis of alkyl and aryl azides, and the development of a new monolithic triphenylphosphine reagent, which provides a convenient format for the use of this versatile reagent in flow. The utility of these new tools was demonstrated by their application to a flow Staudinger aza-Wittig reaction sequence. Finally, a multistep aza-Wittig, reduction and purification flow process was designed, allowing access to amine products in an automated fashion.
