70677-96-2Relevant academic research and scientific papers
K2S2O8-promoted C-Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds
Yang, Xue-Yan,Wang, Ruizhe,Wang, Lu,Li, Jianjun,Mao, Shuai,Zhang, San-Qi,Chen, Nanzheng
, p. 28902 - 28905 (2020/08/25)
A novel K2S2O8-promoted C-Se bond formation from cross-coupling under neutral conditions has been developed. A variety of aldehydes and ketones react well using K2S2O8 as the oxidant in the absence of catalyst and afford desired products in moderate to excellent yields. This protocol provides a very simple route for the synthesis of α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds.
One -step Oxidation of Olefins into α-Phenylseleno Carbonyl Compounds
Shimizu, Makoto,Kuwajima, Isao
, p. 3100 - 3105 (2007/10/02)
Oxidation of olefins has been examined with the following three types of reagents; (i) (C6H5Se)2-Br2-(Bu3Sn)2O, (ii) (C6H5Se)2-t-BuOOH, and (iii) (C6H5Se)2-(C6H5SeO)20, and the corresponding α-phenylseleno carbonyl compounds have been obtained directly from the olefins.
