706786-86-9Relevant academic research and scientific papers
Cul/N,N-dimethylglycine-catalyzed coupling of vinyl halides with amides or carbamates
Pan, Xianhua,Cai, Qian,Ma, Dawei
, p. 1809 - 1812 (2007/10/03)
Matrix presented. The Cul-catalyzed coupling reaction of vinyl halides with amides or carbamates proceeds well at room temperature to 80°C in dioxane to give enamides using N,N-dimethylglycine as the promoter and Cs 2CO3 as the base.
Nickel catalyzed addition of -NH- containing compounds to vinyl and aryl halides
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Page 9, (2008/06/13)
A process for producing unsaturated nitrogen containing compounds such as enamides, enamines and aryl amines/amides is disclosed. A vinyl halide or aryl halide is reacted with an -NH- containing compound in the presence of a catalytic amount of a catalyst precursor composition comprising zero-valent nickel and an organophosphine ligand. One step coupling of vinyl halides and aryl halides with -NH- containing compounds is made possible by practice of this invention.
