70680-88-5

Upstream product

• 934-30-5 5-norbornene-endo-2-carboxylic acid 
• 120-74-1 5-carboxybicyclo<2.2.1>hept-2-ene 

Downstream Products

• 78422-79-4 N-benzyl aza-4 brendanone-5 
• 258345-33-4 6endo-Hydroxy-2exo-norbornancarbonsaeure 
• 81523-34-4 6-endo-(acetoxymethyl)-2-norbornanone 
• 81523-31-1 6-endo-(Hydroxymethyl)bicyclo<2.2.1>heptan-2-one 
• 286456-64-2 (1S,3R,6S,7R)-5-Oxo-4-aza-tricyclo[4.2.1.0^3,7]nonane-3-carboxylic acid 
• 78422-84-1 (1S,3S,6S,7S,9S)-4-Benzyl-9-hydroxy-4-aza-tricyclo[4.2.1.0^3,7]nonan-5-one 
• 78422-89-6 (1R,3R,6S,7R,9R)-4-Benzyl-4-aza-tricyclo[4.2.1.0^3,7]nonan-9-ol 

Relevant academic research and scientific papers

Discovery of chemoselective and biocompatible reactions using a high-throughput immunoassay screening

An immunoassay-based method was used to screen numerous combinations of dipoles and dipolarophiles for their ability to undergo chemoselective and biocompatible [3+2] cycloaddition reactions. The approach fulfills most of the requirements of the click concept and led to the discovery of a copper-catalyzed reaction that generates pyrazoles from sydnone and alkyne reagents. Copyright

Monoamine oxidase-catalyzed oxidation of endo,endo-2-amino-6-[(Z)-2'-phenyl]ethenylbicyclo[2.2.1]heptane, a potential probe for a radical cation intermediate

An 11-step synthesis of endo,endo-2-amino-6-[(E)-2'-phenyl]ethenylbicyclo[2.2.1]heptane (6) and the corresponding (Z)-isomer (7) was carried out in an attempt to make a compound that could trap the purported amine radical cation intermediate during monoamine oxidase (MAO)-catalyzed oxidation of amines. The E-isomer was not a substrate for MAO, and the Z-isomer was a very poor substrate. No trapping product was observed. Possible explanations for the inability of these compounds to trap a potential radical cation intermediate are discussed. Copyright (C) 2000 Elsevier Science Ltd.