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REACTION OF DIAZONIUM SALTS WITH THE TETRACYANOQUINODIMETHANE ANION-RADICAL
Bespalov, B. P.
, p. 736 - 740 (2007/10/02)
Diazonium salts react with the tetracyanoquinodimethane anion-radical with the release of nitrogen and the formation of 1,2-bis-1,1,2,2-tetracyanoethane, where R = H, Me OMe, Cl, CN, NO2, NMe2.During the pyrolysis of these compounds and subsequent irradiation of the reaction mass with UV light 7-(4-R-phenyl)-7,8,8-tricyanoquinodimethanes (R = H, Me, Cl, OMe, NMe2) were obtained with small yields.
