7069-15-0Relevant academic research and scientific papers
Iron-catalyzed alkylations of aromatic Grignard reagents
Cahiez, Gerard,Habiak, Vanessa,Duplais, Christophe,Moyeux, Alban
, p. 4364 - 4366 (2008/03/12)
(Chemical Equation Presented) Any old iron: Two efficient iron-catalyzed cross-coupling reactions between aryl Grignard reagents and alkyl bromides were developed that are suitable for large-scale applications. The first procedure uses iron acetylacetonate and involves a cooperative effect between the two ligands N,N,N′,N′-tetramethylethylenediamine (TMEDA) and hexamethylenetetraamine (HMTA), while the second procedure uses [(FeCl 3)2(tmeda)3] as catalyst. 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Reduction of Monobenzylic Alcohols with Sodium Borohydride/Trifluoroacetic Acid
Nutaitis, Charles F.,Bernardo, Joseph E.
, p. 487 - 493 (2007/10/02)
Sodium borohydride/trifluoroacetic acid readily effects the reduction of monobenzylic alcohols to afford the corresponding hydrocarbons in moderate to high yields.
