7070-92-0

Upstream product

• 90-02-8 salicylaldehyde 
• 540-63-6 ethane-1,2-dithiol 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 90-02-8 salicylaldehyde 
• 169699-29-0 2-(2-chloroacetoxyphenyl)-1,3-dithiolane 
• 169699-30-3 2-<2-(diethoxyphosphoryl)acetoxyphenyl>-1,3-dithiolane 
• 169699-31-4 2-<(diethoxyphosphoryl)acetoxy>benzaldehyde 

Relevant academic research and scientific papers

Crystallinity after decarboxylation of a metal-carboxylate framework: indestructible porosity for catalysis

We report a curious case study of a Zr(iv)-carboxylate framework, which retains significant crystalline order after cascade thermocyclization of its linker components, and - more notably - after the crucial carboxylate links were severed by heat. Vigorous heat treatment (e.g., 450 °C and above) benzannulates the multiple alkyne groups on the linker to generate linked nanographene blocks and to afford real stability. The resultant Zr oxide/nanographene hybrid solid is stable in saturated NaOH and concentrated H3PO4, allowing a convenient anchoring of H3PO4into its porous matrix to enable size-selective heterogeneous acid catalysis. The Zr oxide components can also be removed by strong hydrofluoric acid to further enhance the surface area (up to 650 m2g?1), without collapsing the nanographene scaffold. The crystallinity order and the extensive thermal transformations were characterized by X-ray diffraction, scanning transmission electron microscopy (STEM), IR, solid state NMR and other instrumental methods.

Chemoselective dithioacetalization of carbonyl compounds using magnesium hydrogensulfate as efficient heterogeneous catalyst

Carbonyl compounds have been successfully converted into their corresponding dithiolanes and dithianes derivatives with 1,2-ethanedithiol and 1,3-propanedithiol in excellent yield at room temperature and short reaction times using a catalytic amount of ma

Chemoselective and solvent-free thioacetalization of aldehydes by a catalytic amount of NBS

A chemoselective, straightforward, and rapid method for thioacetalization of aldehydes by use of 1,2-ethandithiol and a catalytic amount of N-bromosuccinimide under solvent-free conditions is reported. The reaction takes place in excellent yields and shor

A mild and chemoselective catalyst for thioacetalization under solvent free conditions

Protection of a variety of carbonyl compounds as dithioacetals using P 2O5/SiO2 (75%), as a mild and chemoselective catalyst, was achieved under solvent free conditions in very good yields. Copyright Taylor & Francis Group

Chemoselective thioacetalisation and transthioacetalisation of carbonyl compounds catalysed by tetrabutylammonium tribromide (TBATB)

Thioacetals and thioketals of various aldehydes and ketones were obtained directly from carbonyl compounds or by a transthioacetalisation process from cyclic O,O-acetals in the presence of dithiols and a catalytic amount of tetrabutylammonium tribromide (TBATB). Chemoselective thioacetalisation of aromatic aldehydes containing an electron-donating group in the presence of an aldehyde containing an electron-withdrawing group, aldehydes in the presence of ketones, aliphatic cyclic ketones in the presence of aromatic ketones and less hindered ketones in the presence of more hindered ketones have been achieved. A cyclic acetal containing an electron-donating group has been chemoselectively transthioacetalised in the presence of an acetal having an electron-withdrawing substituent. These selectivities are due to the intrinsic reactivity of the substrate themselves and are independent of the catalyst and reaction conditions, Shorter reaction times, mild reaction conditions, stability of acid sensitive protecting groups, high efficiencies, facile isolation of the desired products and the catalytic nature of the reagent are the attractive features of the present method.

Promotion of 1,3-Dithiolanes using a Bentonitic Clay as Catalyst

The reactions between 1,2-ethandithiol with several carbonylic compounds to form the corresponding 1,3-dithiolanes were performed using a natural clay as promotor. The target molecules are used as reagents to obtain fine chemicals, herbicides, fungicides,

2,4,4,6-Tetrabromo-2,5-cyclohexadienone (TABCO), N-bromosuccinimide (NBS) and bromine as efficient catalysts for dithioacetalization and oxathioacetalization of carbonyl compounds and transdithioacetalization reactions

The use of 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TABCO), N-bromosuccinimide (NBS), and bromine as efficient catalysts for conversion of carbonyl compounds to their cyclic and acyclic dithioacetals and 1,3-oxathiolanes under mild reaction conditions are described. These catalysts are also used for efficient transdithioacetalization of acetals, diacetals, ketals, acylals, enamines, hydrazones, and oximes with high yields in the presence of thiols.

A rapid and efficient method of thioacetalization of carbonyl compounds catalysed by POCl3-montmorillnite

Aldehydes and ketones were thioactalized with 1,2-ethanedithiol in the presence POCl3-montmorillonite at room temperature in excellent yields.

Highly efficient dithioacetalization of carbonyl compounds catalyzed with iodine supported on neutral alumina

Aldehydes and ketones are protected as their corresponding dithioacetals with ethane-1,2-dithiol in the presence of a catalytic amount of iodine supported on neutral alumina surface. This is a high yielding method of carbonyl group protection under mild,

Solvent free thioacetalization of carbonyl compounds catalyzed by Cu(OTf)2-SiO2

Aldehydes and ketones were thioacetalyzed using 1,2-ethanedithiol in the presence of a catalytic amount of Cu(OTf)2-SiO2 under solvent free conditions in excellent yields.