70717-91-8

Upstream product

• 78086-64-3 4-O-Acetyl-1,5-anhydro-2,6-didesoxy-3-C-methyl-D-arabino-hex-1-enit 
• 6752-48-3 methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 75810-02-5 Methyl-3-O-(4-O-acetyl-2,6-didesoxy-2-iod-3-C-methyl-α-D-mannopyranosyl)-4-O-benzoyl-6-brom-2,6-didesoxy-α-D-arabino-hexopyranosid 
• 75810-03-6 Methyl-3-O-(4-O-acetyl-2,6-didesoxy-3-C-methyl-α-D-arabinohexopyranosyl)-4-O-benzoyl-2,6-didesoxy-α-D-arabino-hexopyranosid 

Relevant academic research and scientific papers

Syntheses and Reactions of 3-C-Methyl-branched Glycals of the D-Series. Preparations of the Isomers of Terminal Disaccharides in Olivomycin A and Mithramycin

Syntheses of D-olivomycal (6) and D-mycaral (9) are achieved starting with D-rhamnal (4) or D-digitoxal (5), respectively.The transformation of 9 to methyl α-D-mycaroside (12) represents a configurational assignment at the branching point.With methyllithi