70719-17-4Relevant academic research and scientific papers
Selective oxidation of alcohol-d1to aldehyde-d1using MnO2
Kitsuwa, Kohei,Kumadaki, Katsushi,Nakayama, Atsushi,Okamura, Hironori,Ozawa, Keita,Shinada, Tetsuro,Tamura, Yusaku,Yamamoto, Yuki,Yasuno, Yoko
, p. 28530 - 28534 (2021/09/22)
The selective oxidation of alcohol-d1to prepare aldehyde-d1was newly developed by means of NaBD4reduction/activated MnO2oxidation. Various aldehyde-d1derivatives including aromatic and unsaturated ald
Nickel phthalocyanine assisted highly efficient and selective carbonyl reduction in polyethylene glycol-400
Verma, Praveen Kumar,Sharma, Upendra,Kumar, Neeraj,Bala, Manju,Kumar, Vishal,Singh, Bikram
scheme or table, p. 907 - 913 (2012/10/07)
Nickel phthalocyanine with polyethylene glycol- 400 is described as a reusable green catalytic system for highly chemo- and regioselective reduction of carbonyl compounds to corresponding alcohols at room temperature. The catalytic system showed wide substrate scope covering aromatic, hetero aromatic and aliphatic carbonyl compounds with high turnover number and frequency. In the present study, 1,3- and 1,4-benzenedicarbaldehydes have been regioselectively reduced to corresponding alcohols for the first time. The catalyst was reused up to seven times without any significance loss in activity. Springer Science+Business Media, LLC 2012.
Microwave Enhanced Deuteriations in the Solid State using Alumina Doped Sodium Borodeuteride
Erb, Wouter Th.,Jones, John R.,Lu, Shui-Yu
, p. 728 - 729 (2007/10/03)
A number of deuterated alcohols are rapidly (ca. 1 min) synthesized through the microwave enhanced solid state reduction of the corresponding aldehydes and ketones using alumina doped sodium borodeuteride (NaBD4).
Photoredox chemistry of nitrobenzyl alcohols in aqueous solution. Acid and base catalysis of reaction
Peter, Wan,Yates, Keith
, p. 2076 - 2086 (2007/10/02)
The photochemistry of several m- and p-nitrobenzyl alcohols (1-5) has been studied in aqueous solution.These compounds react via an intramolecular photoredox pathway to give reduced and oxidized moieties of the substituent groups.The reaction is an example of a new type of photoreaction of nitro-substituted aromatic derivates that is not observed in organic solvents, the presence of water being essential.This effect is exemplified by measuring the quantum efficiency as a function of molpercent water in aqoeous acetonitrile, methanol, and formaldehyde: the reaction efficiency decreases rapidly as water is depleted in the mixture.Catalytic efficts due to the hydronium and hydroxide ions were studied: the para derivatives exhibited hydroxide ion catalysis; the meta derivatives exhibited hydroniumn ion catalysis.Quantum yields, solvent isotop effects, and α-deuterium isotope effects are reported for the parent derivatives.
Kinetics and Stereochemistry of Elimination of Nitrous Acid from 1-p-Nitrophenyl-2-nitroethyl Derivatives
Norris, Robert K.,Wright, Timothy A.
, p. 281 - 294 (2007/10/02)
The eliminations of nitrous acids from the compounds (1) and (6) are E2 processes, which proceed with a large primary kinetic isotope effect and with antiperiplanar stereochemistry.The rate of elimination of HNO2 fom (1) is intermediate between the rate o
