70779-51-0Relevant academic research and scientific papers
Catalytic asymmetric hydrogenation of α-arylcyclohexanones and total synthesis of (-)-α-lycorane
Li, Gang,Xie, Jian-Hua,Hou, Jing,Zhu, Shou-Fei,Zhou, Qi-Lin
supporting information, p. 1597 - 1604 (2013/07/05)
An efficient catalytic asymmetric hydrogenation of racemic α-arylcyclohexanones with an ethylene ketal group at the 5-position of the cyclohexane ring via dynamic kinetic resolution has been developed, giving chiral α-arylcyclohexanols with two contiguous
A Synthesis of Seco-mesembrane Alkaloids, (+/-)-Joubertiamine, (+/-)-Joubertinamine, and (+/-)-Epijoubertinamine
Hoshino, Osamu,Ishizaki, Miyuki,Sawaki, Shohei,Yuasa, Masayuki,Umezawa, Bunsuke
, p. 3373 - 3380 (2007/10/02)
A synthesis of seco-mesembrane alkaloids, (+/-)-joubertiamine (4), (+/-)-joubertinamine (5), and (+/-)-epijoubertinamine (6), was accomplished starting with 2-allyl-2-aryl-5,5-ethylenedioxycyclohexanones (10 and 3), which are readily available by allylati
Synthesis of Sceletium and Amaryllidaceae Alkaloids, (+/-)-Mesembrine and (+/-)-Dihydromaritidine, (+/-)-Epidihydromaritidine, (+/-)-Elwesine, and (+/-)-Epielwesine
Hoshino, Osamu,Sawaki, Shohei,Shimamura, Naomi,Onodera, Akira,Umezawa, Bunsuke
, p. 2734 - 2743 (2007/10/02)
The alkylation of 2-arylcyclohexanones (12b and 6) with alkyl halides or acrylonitrile and 50percent aq. sodium hydroxide in the presence of a phase-transfer catalyst (18-crown-6) was found to give readily 2-alkyl-2-arylcyclohexanones (14 and 16) in fair
