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1,4-Naphthalenedione, 2-[[(4-methylphenyl)sulfonyl]oxy]-, also known as 2-(4-Methylphenylsulfonyloxy)-1,4-naphthoquinone, is a chemical compound with the molecular formula C16H12O4S. It is a derivative of 1,4-naphthoquinone, featuring a sulfonyl group attached to the 2-position of the naphthalene ring. This sulfonyl group consists of a 4-methylphenyl group connected to an oxygen atom, which in turn is connected to another oxygen atom. The compound is characterized by its yellow crystalline appearance and is soluble in organic solvents. It is primarily used as an intermediate in the synthesis of various pharmaceuticals and agrochemicals, particularly those involving the naphthalene core structure. Due to its reactivity and functional groups, it plays a significant role in the development of new compounds with potential applications in various industries.

70871-48-6

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70871-48-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 70871-48-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,0,8,7 and 1 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 70871-48:
(7*7)+(6*0)+(5*8)+(4*7)+(3*1)+(2*4)+(1*8)=136
136 % 10 = 6
So 70871-48-6 is a valid CAS Registry Number.

70871-48-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,4-naphthalenedione, 2-[[(4-methylphenyl)sulfonyl]oxy]

1.2 Other means of identification

Product number -
Other names 2-Tosyloxy-1,4-naphthochinon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:70871-48-6 SDS

70871-48-6Downstream Products

70871-48-6Relevant academic research and scientific papers

Molecular anchors - Mimicking metabolic processes in thiol analysis

Smith, Robert B.,Canton, Claire,Lawrence, Nathan S.,Livingstone, Callum,Davis, James

, p. 1718 - 1724 (2006)

The interaction between various novel naphthoquinones and glutathione was explored using a variety of electrochemical techniques. An adamantane derivatised quinone was found to adsorb strongly to carbon surfaces providing a robust film possessing a distin

Synthesis, biological evaluation, and correlation of cytotoxicity versus redox potential of 1,4-naphthoquinone derivatives

Shen, Chien-Chang,Afraj, Shakil N.,Hung, Chia-Cheng,Barve, Balaji D.,Kuo, Li-Ming Yang,Lin, Zhi-Hu,Ho, Hisu-O.,Kuo, Yao-Haur

supporting information, (2021/04/12)

A series of 1,4-naphthoquinone derivatives of lawsone (1), 6-hydroxy-1,4-naphthoquinone (2), and juglone (3) were synthesized by alkylation, acylation, and sulfonylation reactions. The yields of lawsone derivatives 1a-1k (type A), 6-hydroxy-1,4-naphthoqui

1,4-Naphthoquinones, VII: C-Methylation of 1,4-Naphthoquinones

Wurm, Gotthard,Geres, Uwe

, p. 606 - 609 (2007/10/02)

The action of Fenton's reagent on dimethyl sulfoxide results in carbon methylation of the quinoid system of 1,4-naphthoquinones by .CH3 under particularly mild conditions.The results depend on the substitution pattern at positions 2 and 3 and on the suitable protection of the OH group at position 5.

Photochemical Reactivity of α-Sulfonyloxy Enones: An Easy Method for Arylation of 1,2-Diketones

Feigenbaum, Alexandre,Pete, Jean-Pierre,Scholler, Denise

, p. 2355 - 2360 (2007/10/02)

3-Aryl-1,2-cyclohexanediones 4 are prepared conveniently by photolysis of the corresponding 2-((arylsulfonyl)oxy)cyclohex-2-enones 1.The reaction was shown to occur from a triplet excited state.A biphotonic process involving the normal photo-Fries product 14 as an intermediate was ruled out by preparing and irradiating this compound.The difference of reactivity between 1 and 2-((arylsulfonyl)amido)cyclohexenones is discussed.

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