70897-33-5

Upstream product

• 2622-14-2 tricyclohexylphosphine 
• 52637-54-4 chlorodihydridobis(tricyclohexylphosphine)rhodium(III) 
• 10049-07-7 rhodium(III)chloride 
• 12092-47-6 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 
• 63683-89-6 RhCl(tricyclohexylphosphine)2 

Downstream Products

• 17966-79-9 RhCl(CO)(tricyclohexylphosphine)2 
• 85420-60-6 carbonyldichlorohydridobis(tricyclohexylphosphine)rhodium(II) 
• 85420-59-3 carbonyldichlorobis(tricyclohexylphosphine)rhodium(II) 
• 17966-79-9 trans-((C₆H₁₁)3P)2Rh(CO)Cl 

Relevant academic research and scientific papers

Rhodium(III) biphasic and phase-transfer-catalyzed hydrogenolysis of chloroarenes under exceptionally mild conditions

The rhodium (III) complexes L2Rh(H)Cl2 [L = tricyclohexylphosphine or triisopropylphosphine] are excellent catalysts for the hydrogenolysis of chlorparenes. The reaction proceeds under biphasic [40% NaOH, PhCH3] conditions

Tertiary phosphine complexes of rhodium(I) and rhodium(III) chlorides

The most complete series of tertiary phosphine complexes of rhodium yet reported has been prepared. Depending on the particular phosphine and the method of preparation, several different types of complexes may be formed. These include RhCl3(PR