70912-46-8Relevant academic research and scientific papers
New Access Routes to Privileged and Chiral Ligands for Transition-Metal Catalyzed Hydrogen Autotransfer (Borrowing Hydrogen), Dehydrogenative Condensation, and Alkene Isomerization Reactions
Hintermann, Lukas,Jandl, Christian,Klein, Philippe,Koller, Sebastian,Ochmann, Lukas,P?thig, Alexander,Reinhardt, Katja,Seitz, Antonia
, (2021/11/30)
A group of transition-metal catalyzed hydrogen moving reactions, encompassing hydrogen autotransfer (HAT; also called borrowing hydrogen, BH), dehydrogenative condensation (DHC) and alkene isomerization, displays high atom economy and relies on widely ava
Nucleophilic Substitution with Phosphide Anions Prepared by an Action of Sodium Dihydridobis(2-methoxyethanolato)aluminate on Phosphorus Compounds
Yamashita, Mitsuji,Suzuki, Nobuyoshi,Yamada, Manabu,Soeda, Yukio,Yamashita, Hiroaki,et al.
, p. 219 - 222 (2007/10/02)
Phosphide anions, prepared by an action of sodium dihydridobis(2-methoxyethanolato)aluminate on derivatives of phosphine, phosphine oxide, or phosphorus esters, react with primary and secondary alkyl halides to produce phosphine derivatives having a newly formed phosphorus-carbon bond.The reactivity increases in the order of chloride N2 type process.
