7096-96-0Relevant academic research and scientific papers
Divergent Entry to Gelsedine-Type Alkaloids: Total Syntheses of (-)-Gelsedilam, (-)-Gelsenicine, (-)-Gelsedine, and (-)-Gelsemoxonine
Wang, Pingluan,Gao, Yang,Ma, Dawei
, p. 11608 - 11612 (2018/09/21)
The gelsedine-type alkaloids possess a common oxabicyclo[3.2.2]nonane core and spiro-N-methoxyindolinone moiety along with a diversely functionalized heterocycle embedded in the compact framework. Herein we disclose a divergent entry to gelsedine-type alk
Unified Total Synthesis of Five Gelsedine-Type Alkaloids: (-)-Gelsenicine, (-)-Gelsedine, (-)-Gelsedilam, (-)-14-Hydroxygelsenicine, and (-)-14,15-Dihydroxygelsenicine
Harada, Takaaki,Shimokawa, Jun,Fukuyama, Tohru
supporting information, p. 4622 - 4625 (2016/09/28)
The systematic arrangement of a two-carbon unit, hydrogen atom, and oxygen atom on the versatile enal moiety of a non-natural synthetic intermediate successfully led to the unified access to the gelsedine-type alkaloids. The development and use of this ne
