71046-80-5Relevant academic research and scientific papers
Regio- and stereoselective stevens rearrangement of benzyltetrahydroprotoberberinium salts
Valpuesta, Maria,Diaz, Amelia,Suau, Rafael,Torres, Gregorio
, p. 4313 - 4318 (2004)
8-(Arylmethyl)berbines are conveniently obtained through a Stevens rearrangement of the corresponding N-arylmethylberbinium salts with sodium methylsulfinylmethylide in DMSO. This procedure has provided two new nonnatural 8-benzylcanadines stereoselectively, without competition from the Hofmann elimination. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
