711014-90-3

Upstream product

• 622-95-7 4-chlorobenzyl bromide 
• 40861-08-3 N,N-bis(p-chlorobenzyl)hydroxylamine 

Downstream Products

• 51307-68-7 N-4-chlorobenzylhydroxylamine 
• 104-88-1 4-chlorobenzaldehyde 

Relevant academic research and scientific papers

S -Tetrazine: Robust and Green Photoorganocatalyst for Aerobic Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones

Efficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range of nitrones in high yields under mild conditions. In addition, an oxidative (3+3) cycloaddition between an oxyallyl cation precursor and a hydroxylamine was also developed.

Novel preparation of N-arylmethyl-N-arylmethyleneamine N-oxides from benzylic bromides with zinc and isobutyl nitrite

Treatment of benzylic bromides with Zn and LiCl, followed by the reaction with i-butyl nitrite gave N-arylmethyl-N-arylmethyleneamine N-oxides in moderate yields. The present reaction is a novel and simple method for the preparation of nitrones from benzylic bromides, although the yields are moderate.

Mechanism of the 10-methylacridinium ion-sensitized photooxidation of N,N-dibenzylhydroxylamine and its derivatives in acetonitrile

The 10-methylacridinium ion (MA+)-sensitized photooxidation of substituted N,N-dibenzylhydroxylamines (1) in acetonitrile occurred mainly by a superoxide ion mechanism to give N-benzylidenebenzylamine N-oxides (2) and hydrogen peroxide quantitatively. Analysis of substituent effects on the limiting quantum yield for formation of 2 showed that back electron transfer (ET) from the 10-methylacridinyl radical (MA.) to the radical cation 1+. proceeds in the Marcus 'normal region'. In addition, this back ET was found to take place in preference to one-electron reduction of O2 by MA..

Cyanoanthracene-sensitized Photooxidations of N,N-Dibenzylhydroxylamine and its Derivatives: Free-energy Dependence of Back Electron-transfer Rates within Geminate Radical Ion Pairs

The fluorescence of 9-cyanoanthracene (CA) and 9,10-dicyanoanthracene (DCA) is quenched by the title hydroxylamine 1 in acetonitrile according to the Stern-Volmer equation.An analysis of the Rehm-Weller plot of the bimolecular quenching rate constant agai

Cyanoanthracene-sensitized Photooxidations of N,N-Dibenzylhydroxylamine and its Derivatives; Observation of the Marcus 'Inverted Region' in Back Electron Transfer within Geminate Radical Ion Pairs

Back electron transfer within geminate radical ion pairs formed by electron transfer from the title hydroxylamines to singlet 9-cyano- and 9,10-dicyano-anthracenes in acetonitrile is shown to occur in the Marcus 'inverted region' and 'normal region', resp