71193-02-7Relevant academic research and scientific papers
INVESTIGATION OF THE SALTS FORMED AS A RESULT OF THE REACTION OF HETEROCUMULENES CO2, COS, AND CS2 WITH SECONDARY AMINES BY 13C AND 1H NMR
Savin, V. P.,Talzi, V. P.,Bek, N. O.
, p. 1680 - 1688 (2007/10/02)
The properties of the salts formed as a result of the reactions of carbon dioxide, carbon sulfoxide and carbon disulfide with dimethyl-, diethyl-, dipropyl-, ethylcyclohexyl-, and dicyclohexylamines, morpholine, piperidine, and hexamethyleneimine were investigated by 13C and 1H NMR methods.The free energies of activation were obtained for restricted rotation about the N-COS bond in the thiocarbamate ions of the alkylammonium thiocarbamates and also for the formation and decomposition of the carbamate ions of the alkylammonium carbamates.
