71194-27-9

Basic information

• Product Name: Decanoic acid, 10-chloro-, methyl ester
• CAS NO: 71194-27-9
• Molecular Formula: C11H21ClO2
• Molecular Weight: 220.74
• Mol File: 71194-27-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Decanoic acid, 10-chloro-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Decanoic acid, 10-chloro-, methyl ester(71194-27-9)
• EPA Substance Registry System: Decanoic acid, 10-chloro-, methyl ester(71194-27-9)

Safety Data

• Hazardous Substances Data: 71194-27-9(Hazardous Substances Data)

Upstream product

• 111-81-9 Methyl 10-undecenoate 

Downstream Products

• 37027-56-8 10-chlorodecanoic acid 
• 1679-53-4 10-hydroxydecanoic acid 

Relevant articles and documents

METATHESIS REACTIONS OF UNSATURATED ESTERS CATALYZED BY HOMOGENEOUS TUNGSTEN COMPLEXES. SYNTHESES OF CIVETONE AND MACROLIDES

The metathesis reactions of methyl 10-undecenoate, methyl oleate and oleyl acetate have been carried out using WCl6 and WOCl4 as primary catalysts and SnMe4, PbMe4, Cp2TiMe2, and Cp2ZrMe2 as cocatalysts.The catalyst system WOCl4/Cp2TiMe2 was found to be very active for the metathesis of the unsaturated esters and is somewhat better than the system WCl6/SnMe4.Diethyl 9-octadecene-1,18-dioate, obtained by the metathesis of ethyl oleate, was subjected to the Dieckmann cyclization.The cyclized product was decarboxylated to give civetone as a mixture of the cis and trans isomers.Preliminary studies of macrolide synthesis by the intramolecular metathesis of oleyl oleate and 10-undecenyl 10-undecenoate to afford 9-octadecen-18-olide and 10-eicosen-20-olide, respectively, have been carried out.