712-99-2Relevant academic research and scientific papers
An Efficient Biocatalyzed Kinetic Resolution of Methyl (Z)-3-Arylsulphinylpropenoates
Cardellichio, Cosimo,Naso, Francesco,Scilimati, Antonio
, p. 4635 - 4638 (2007/10/02)
The enzymatic hydrolysis of racemic methyl (Z)- and (E)-3-arylsulphinylpropenoates by several microbial lipases and α-chymotrypsin (α-CHT) was studied.High enantioselectivity values (up to 99percent) were obtained using (Z)-methyl esters.
DIASTEREOSELECTIVE DIELS-ALDER REACTIONS OF OPTICALLY-ACTIVE VINYL SULPHOXIDES
Brimble, Margaret A.,Davis, Brian R.
, p. 4965 - 4972 (2007/10/02)
The Diels-Alder reaction of an optically active vinyl sulphoxide containing a second electron withdrawing group with cyclopentadiene gave separable diastereomers.The effect of Lewis acid catalysis on the reaction was studied.Reaction of an acetylenic anio
