712280-95-0

Upstream product

• 712280-91-6 (1S,4R,6S)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-1-[3',4'-(methylenedioxy)phenyl]-2-cyclohexen-1-ol 
• 712281-01-1 (1R,4R,6S)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-1-[3',4'-(methylenedioxy)phenyl]-2-cyclohexen-1-ol 
• 712280-93-8 (1R,4S,6R)-4-benzyloxy-6-(tert-butyldimethylsilyloxy)-3-[3',4'-(methylenedioxy)phenyl]-2-cyclohexen-1-ol 
• 712280-92-7 (4S,6R)-4-benzyloxy-6-(tert-butyldimethylsilyloxy)-3-[3',4'-(methylenedioxy)phenyl]-2-cyclohexen-1-one 
• 17680-04-5 (3,4-methylenedioxy)phenylmagnesium bromide 
• 712280-94-9 {(1S,4R,6S)-1-[3',4'-(methylenedioxy)phenyl]-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-2-cyclohexenyl}acetic acid ethyl ester 

Downstream Products

• 510-67-8 vittatine 
• 712280-97-2 N-(tert-butoxycarbonyl)-N-{2-(1'S,4'R,6'S)-1'-[3,4-(methylenedioxy)phenyl]-4'-(tert-butyldimethylsilyloxy)-2'-cyclohexenyl}ethyl amine 
• 712280-96-1 N-(tert-butoxycarbonyl)-N-{2-(1'S,4'R,6'S)-1'-[3,4-(methylenedioxy)phenyl]-6'-benzyloxy-4'-(tert-butyldimethylsilyloxy)-cyclohex-2'-enyl}ethyl-N-(p-toluenesulfonyl)-amine 

Relevant academic research and scientific papers

Total synthesis of Amaryllidaceae alkaloids, (+)-vittatine and (+)-haemanthamine, starting from d-glucose

The stereoselective total synthesis of (+)-vittatine 1 and (+)-haemanthamine 2 starting from d-glucose is described. The cyclohexene ring in 1 was prepared in an optically active form from d-glucose using Ferrier's carbocyclization reaction, and the criti

A new entry to Amaryllidaceae alkaloids from carbohydrates: total synthesis of (+)-vittatine.

The stereoselective and chiral synthesis of the Amaryllidaceae alkaloid, (+)-vittatine 1, is described; the quaternary carbon in 1 was generated by Claisen rearrangement of a cyclohexenol derived from D-glucose by way of a Ferrier's carbocyclisation react