71312-19-1

Basic information

• Product Name: 3-Buten-2-ol, 3-methyl-1-(phenylmethoxy)-
• CAS NO: 71312-19-1
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol File: 71312-19-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-ol, 3-methyl-1-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-ol, 3-methyl-1-(phenylmethoxy)-(71312-19-1)
• EPA Substance Registry System: 3-Buten-2-ol, 3-methyl-1-(phenylmethoxy)-(71312-19-1)

Safety Data

• Hazardous Substances Data: 71312-19-1(Hazardous Substances Data)

Upstream product

• 58558-53-5 (((3-methylbut-3-en-1-yl)oxy)methyl)benzene 
• 14593-43-2 benzyl allyl ether 
• 71312-15-7 3-((benzyloxy)methyl)-2,2-dimethyloxirane 
• 60656-87-3 benzyloxyacetoaldehyde 
• 13291-18-4 isopropenylmagnesium bromide 
• 22089-60-7 benzyl prenyl ether 

Downstream Products

• 130252-85-6 (R)-2-Benzyloxy-1-((S)-2-methyl-oxiranyl)-ethanol 
• 103791-04-4 Benzyloxymethyl isopropenyl ketone 
• 1627156-60-8 C₁₄H₁₆Cl₃NO₂ 
• 1627156-73-3 C₂₀H₂₁NO₄ 
• 130252-86-7 Naphthalene-1-carboxylic acid (R)-2-benzyloxy-1-((S)-2-methyl-oxiranyl)-ethyl ester 
• 130252-87-8 Naphthalene-1-carboxylic acid ((2S,3R)-4-benzyloxy-2,3-dihydroxy-2-methyl-butyl)-amide 
• 98713-71-4 ((E)-3-Methyl-oct-2-enyloxymethyl)-benzene 
• 75593-35-0 ((E)-3-Methyl-pent-2-enyloxymethyl)-benzene 
• 53651-97-1 benzyl 3,7-dimethylocta-2,7-dienyl ether 
• 91892-28-3 benzyl 8-hydroxy-3,7-dimethyloct-2-enyl ether 
• 91892-25-0 benzyl 2-isopropenyl-5-methylhex-5-enyl ether 
• 68268-90-6 benzyl 2-isopropenyl-5-methylhex-4-enyl ether 
• 31162-70-6 benzyl geranyl ether 
• 106-25-2 Nerol 

Relevant articles and documents

Proton-accelerated Lewis acid catalysis for stereo- And regioselective isomerization of epoxides to allylic alcohols

The isomerization of epoxides to allylic alcohols was developedviaproton-accelerated Lewis acid catalysis. The addition oftBuOH as a proton source is the key to the efficient catalytic cycle. Trisubstituted epoxides, including enantioenriched derivatives, were selectively converted to secondary-allylic alcohols without loss of enantiopurity.

Selective isomerization of epoxides to allylic alcohols catalyzed by TiO2-supported gold nanoparticles

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Synthetic studies towards carzinophilin: Synthesis and ammonium hydroxide-induced rearrangement of the epoxi-acid fragment

An efficient synthesis of the epoxide-containing fragment 4 of carzinophilin has been completed. Intramolecular acyl transfer of a related epoxide afforded amide 16. Comparison by 1H NMR of 4 and 16 with authentic natural product provides further evidence for structural revision of carzinophilin.