71344-08-6Relevant academic research and scientific papers
Reaction of isoquinolinium methylide derivatives with trimethylsilylketene
Kobayashi, Mayumi,Tanabe, Mika,Kondo, Kazuhiro,Aoyama, Toyohiko
, p. 1469 - 1471 (2006)
Our investigation on the reaction of isoquinolinium methylide derivatives with trimethylsilylketene (TMS ketene), giving [3+2] cycloadducts, pyrroloisoquinolines, is described. TMS ketene is found to function as the C2 unit introducing reagent in the reaction of isoquinolinium methylide derivatives. Furthermore, the advantage of TMS ketene in comparison with ketene (CH2CO) is shown.
