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71360-06-0

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71360-06-0 Usage

Chemical Properties

Colorless liquid

Uses

Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare: Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones. The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines. Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.

Check Digit Verification of cas no

The CAS Registry Mumber 71360-06-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,1,3,6 and 0 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 71360-06:
(7*7)+(6*1)+(5*3)+(4*6)+(3*0)+(2*0)+(1*6)=100
100 % 10 = 0
So 71360-06-0 is a valid CAS Registry Number.

71360-06-0 Well-known Company Product Price

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  • Aldrich

  • (695157)  Bis(3,5-dimethylphenyl)phosphine  

  • 71360-06-0

  • 695157-100MG

  • 614.25CNY

  • Detail
  • Aldrich

  • (695157)  Bis(3,5-dimethylphenyl)phosphine  

  • 71360-06-0

  • 695157-500MG

  • 2,266.29CNY

  • Detail

71360-06-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis(3,5-dimethylphenyl)phosphine

1.2 Other means of identification

Product number -
Other names bis(3,5-dimethylphenyl)phosphane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:71360-06-0 SDS

71360-06-0Relevant articles and documents

Cinchona alkali ligand and preparation method and application thereof

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Paragraph 0085-0087; 0089; 0093-0096; 0128-0129; 0134; ..., (2021/12/31)

The invention belongs to the field of organic chemical ligands, and particularly relates to a cinchona alkali ligand, which has a structure shown in a general formula I or a tautomer, an enantiomer and a diastereoisomer thereof, in the formula I, R1 is selected from alkyl, alkenyl and -CH = CHPh, R2 is selected from hydrogen, alkyl, phenyl and substituted phenyl, and R is selected from substituted phenyl. The invention also discloses a preparation method and application of the cinchona alkaloid ligand. The ligand disclosed by the invention has advantages in stereoselectivity and reaction efficiency, and a higher ee value and yield can be obtained in an asymmetric reaction.

METHODS FOR PREPARING BIS-TETRAHYDROISOQUINOLINE-CONTAINING COMPOUNDS

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Page/Page column 92; 93, (2019/02/06)

(-)-Jorumycin, ecteinascidin 743, saframycin A and related compounds, methods of preparing the same, formulations comprising the compounds, and methods of treating proliferative diseases with the same are provided.

General and selective copper-catalyzed reduction of tertiary and secondary phosphine oxides: Convenient synthesis of phosphines

Li, Yuehui,Das, Shoubhik,Zhou, Shaolin,Junge, Kathrin,Beller, Matthias

scheme or table, p. 9727 - 9732 (2012/07/14)

Novel catalytic reductions of tertiary and secondary phosphine oxides to phosphines have been developed. Using tetramethyldisiloxane (TMDS) as a mild reducing agent in the presence of copper complexes, PO bonds are selectively reduced in the presence of other reducible functional groups (FGs) such as ketones, esters, and olefins. Based on this transformation, an efficient one pot reduction/phosphination domino sequence allows for the synthesis of a variety of functionalized aromatic and aliphatic phosphines in good yields.

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