714276-69-4

Upstream product

• 714276-78-5 (η5-C5(CH3)5)(1,2,4-tri-n-propylbenzene)ruthenium(II)2,6-dimesitylphenyl thiolate 
• 714276-76-3 (η5-C5(CH3)5)(1,2,4-triphenylbenzene)ruthenium(II) 2,6-dimesitylphenyl thiolate 

Downstream Products

• 714276-70-7 (η5-C5(CH3)5)ruthenium(II)(CNC(CH3)3)2 2,6-mesitylphenyl thiolate 
• 714276-76-3 (η5-C5(CH3)5)(1,2,4-triphenylbenzene)ruthenium(II) 2,6-dimesitylphenyl thiolate 
• 714276-72-9 (η5-C5(CH3)5)(2,2'-bipyridine)ruthenium(II) 2,6-mesitylphenyl thiolate 
• 714276-73-0 (η5-C5(CH3)5)(1,10-phenantroline)ruthenium(II) 2,6-mesitylphenyl thiolate 
• 714276-71-8 (η5-C5(CH3)5)dicarbonylruthenium(II) 2,6-mesitylphenyl thiolate 

Relevant academic research and scientific papers

A half-sandwich ruthenium(II) complex containing a coordinatively unsaturated 2,6-dimesitylphenyl thiolate ligand

Electron-deficient ruthenium complex [Cp*Ru(SDmp)] (1; SDmp = 2,6-dimesitylphenylthiolate, Cp* = η5-C5Me 5) is stabilized by the coordination of Cipso of one mesityl group of SDmp. It serves as a precursor to coordinatively unsaturated species in two ways: by the lability of Cipso in reactions with ligands L, and by reversible dissociation/association of the SDmp ligand in the regioselective cyclotrimerization of substituted alkynes (see scheme).