714293-43-3Relevant academic research and scientific papers
Preparation of bis(diazo) compounds incorporated into butadiyne and thiophene units and generation and characterization of their photoproducts
Morisaki, Fumika,Kurono, Masakuni,Hirai, Katsuyuki,Tomioka, Hideo
, p. 431 - 440 (2007/10/03)
(2,6-Dimethyl-4-tert-butylphenyl)(2,4,6-tribromophenyl)diazomethane(1- N2) was found to be stable enough to survive under Sonogashira coupling reaction conditions, and aryldiazomethyl substituents were introduced at the 1,4-positions of butadiy
Preparation of poly(phenyl)acetylenes having diazo groups and magnetic characterization of poly(carbene)
Itoh, Tetsuji,Jinbo, Yoshinobu,Hirai, Katsuyuki,Tomioka, Hideo
, p. 1650 - 1651 (2007/10/03)
(2,6-Dibromo-4-ethynylphenyl)(2,6-dimethyl-4-tert-butylphenyl)diazomethane was found to be stable enough to survive under Rh-complex-catalyzed polymerization conditions and underwent polymerization to give a phenylacetylene polymer having diazo functional
Synthesis of phenylacetylene dendrimers having sterically congested diazo units and characterization of their photoproducts
Itoh, Tetsuji,Maemura, Toshiyuki,Ohtsuka, Yusuke,Ikari, Yoshiyuki,Wildt, Holger,Hirai, Katsuyuki,Tomioka, Hideo
, p. 2991 - 3003 (2007/10/03)
The compound (4-tert-butyl-2,6-dimethylphenyl)(2,4,6-tribromophenyl) diazomethane (1a), a precursor for persistent triplet carbene, was found to be stable enough to survive Sonogashira coupling reaction conditions to give (4-tertbutyl-2,6-dimethylphenyl)(
Triplet diphenylcarbenes protected by (trimethylsilyl)ethynyl groups
Itoh, Tetsuji,Jinbo, Yoshinobu,Hirai, Katsuyuki,Tomioka, Hideo
, p. 4238 - 4244 (2007/10/03)
(2,4,6-Tribromophenyl)(4-tert-butyl-2,6-dimethylphenyl)diazomethane (1a) was shown to be stable enough to survive Sonogashira coupling reaction conditions at an elevated temperature and gave not only a para-monosubstituted product, (4-trimethylsilylethyny
