71443-54-4Relevant articles and documents
Synthesis of unsymmetrical hetaryl-1,2-diketones
Yusubov, Mehman S,Zholobova, Galina A,Vasilevsky, Sergey F,Tretyakov, Eugene V,Knight, David W
, p. 1607 - 1610 (2002)
Oxidation of the triple bond in 4-alkynylpyrazoles 2a-e and acetylenic derivatives of the crown-ethers 7a,b with PdCl2-DMSO has been carried out to give unsymmetrical hetaryl-1,2-diketones 3a-e; 8a,b. Attempts to oxidize the triple bond in 5-alkynylpyrazole 6 and alkynylpyridines 5a,b and 9 failed.