714959-73-6Relevant academic research and scientific papers
PROCESS FOR PRODUCING AMINOPHOSPHONIC ACID DERIVATIVE
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Page/Page column 8, (2008/06/13)
To present a reaction system that efficiently catalyzes an enantio selective asymmetric nucleophilic addition reaction of an ±-iminophosphonic acid ester. An optically active ±-amino-3-oxophosphonic acid derivative is produced through an asymmetric addition reaction of an ±-iminophosphonic acid ester and a nucleophilic agent (for example, a silyl enol ether).
Catalytic asymmetric synthesis of α-amino phosphonates using enantioselective carbon-carbon bond-forming reactions
Kobayashi, Shu,Kiyohara, Hiroshi,Nakamura, Yoshitaka,Matsubara, Ryosuke
, p. 6558 - 6559 (2007/10/03)
We have developed highly enantioselelctive reactions of silicon enolates with N-acyl-α-iminophosphonates leading to optically active α-amino phophonates. A copper (II)-diamine complex was shown to be effective in this reaction, and high levels of yield an
