714962-74-0Relevant academic research and scientific papers
The construction of halido-bridged dinuclear copper(II) complexes with tridentate schiff bases
Qian, Shao-Song,Lu, Yao,You, Zhong-Lu,Zhu, Hai-Liang
, p. 107 - 110 (2013)
Two new halido-bridged dinuclear copper(II) complexes, [Cu 2Cl2L2]·1.5H2O (1) and [Cu2Br2L2]·H2O (2), where L is the deprotonated form of the Schiff base 4-bromo-2-[(2-hydroxypropylimino) methyl]phenol, have been prepared and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray crystallography. Each Cu atom in the complexes is coordinated by three donor atoms of Schiff bases and by two halide atoms, forming a square pyramidal geometry. The Cl and Br atoms are preferred bridging groups for the construction of dinuclear copper complexes with Schiff bases. Copyright Taylor & Francis Group, LLC 2013.
Synthesis, characterization, and crystal structures of dioxomolybdenum(VI) complexes [MoO2L1(CH3OH)] and [MoO 2L2(CH3OH)] Derived from 4-Halo-2-[(2- hydroxypropylimino)methyl]phenol
Zhang, Hong-Ge
, p. 933 - 936 (2013/07/11)
Two new mononuclear dioxomolybdenum(VI) complexes, [MoO2L 1(CH3OH)] (1) and [MoO2L2(CH 3OH)] (2), have been prepared by the reaction of MoO 2(acac)2 with the tridentate Schiff base ligands 4-chloro-2-[(2-hydroxypropylimino)methyl]phenol (H2L1) and 4-bromo-2-[(2-hydroxypropylimino)methyl]phenol (H2L2), respectively, in methanol. The complexes were characterized by elemental analyses, infrared spectra, and single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic space group with unit cell dimensions a = 6.970(2), b = 10.350(2), c = 10.570(2) A, α = 68.680(3), β = 78.813(3), γ = 77.321(3)°, V = 687.5(3) A3, Z = 2, R1 = 0.0381, and wR2 = 0.0860. Complex 2 crystallizes in triclinic space group with unit cell dimensions a = 7.075(2), b = 10.473(2), c = 10.691(2) A, α = 68.744(3), β = 77.959(3), γ = 76.320(3)°, V = 710.8(3) A3, Z = 2, R1 = 0.0477, and wR2 = 0.1171. Both complexes consist of cis-MoO2 core coordinated by a Schiff base ligand through two deprotonated hydroxyl groups and one imino nitrogen atom. The octahedral coordination around the molybdenum atom is completed by the neutral methanol ligand. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.
