714966-15-1

Basic information

• Product Name: (4R,5R)-1,3-Di-tert-butyl-2-(diazo-trimethylsilanyl-methyl)-4,5-diphenyl-[1,3,2]diazaphospholidine
• Synonyms: (4R,5R)-1,3-Di-tert-butyl-2-(diazo-trimethylsilanyl-methyl)-4,5-diphenyl-[1,3,2]diazaphospholidine
• CAS NO: 714966-15-1
• Molecular Weight: 466.682
• Mol File: 714966-15-1.mol

Chemical Properties

• CAS DataBase Reference: (4R,5R)-1,3-Di-tert-butyl-2-(diazo-trimethylsilanyl-methyl)-4,5-diphenyl-[1,3,2]diazaphospholidine(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5R)-1,3-Di-tert-butyl-2-(diazo-trimethylsilanyl-methyl)-4,5-diphenyl-[1,3,2]diazaphospholidine(714966-15-1)
• EPA Substance Registry System: (4R,5R)-1,3-Di-tert-butyl-2-(diazo-trimethylsilanyl-methyl)-4,5-diphenyl-[1,3,2]diazaphospholidine(714966-15-1)

Safety Data

• Hazardous Substances Data: 714966-15-1(Hazardous Substances Data)

Upstream product

• 18107-18-1 diazomethyl-trimethyl-silane 
• 714966-17-3 (4R,5R)-1,3-Di-tert-butyl-2-chloro-4,5-diphenyl-[1,3,2]diazaphospholidine 

Downstream Products

• 714966-16-2 C₂₆H₃₉N₂PSi 

Relevant articles and documents

Stable Optically Pure Phosphino(silyl)carbenes: Reagents for Highly Enantioselective Cyclopropanation Reactions

The stability of phosphino(trimethylsilyl)carbenes bearing cyclic diamino substituents on phosphorus is strongly dependent on the steric hindrance of the nitrogen substituents. Phosphinocarbenes 3 and 7, derived from the trans-N,N′-diisopropylcyclohexane-