71518-98-4

Usage

Uses

Used in Chemical Synthesis Industry:
1-Chloro-2-Methylenecyclohexane is used as an organic building block for chemical synthesis. Its unique structure allows it to be a versatile intermediate in the production of various organic compounds, including pharmaceuticals, agrochemicals, and specialty chemicals. The allylic chloride functionality makes it a valuable precursor for a wide range of chemical reactions, such as nucleophilic substitution, elimination, and palladium-catalyzed cross-coupling reactions, enabling the synthesis of complex organic molecules with diverse applications.

Upstream product

• 7719-09-7 thionyl chloride 
• 60-29-7 diethyl ether 
• 4845-04-9 1-cyclohexene-1-methanol 
• 936-03-8 trans-2-carbomethoxycyclohexan-1-ol 
• 609-69-8 trans-2-hydroxycyclohexanecarboxylic acid 
• 63301-31-5 trans-2-cyanocyclohexanol 
• 6628-80-4 trans-2-chlorocyclohexanol 
• 1192-37-6 methylenecyclohexane 
• 53723-51-6 1-cyclohexen-1-ylmethyl acetate 
• 33867-02-6 1-chloromethylcyclohexene 
• 930-66-5 1-chlorocyclohexene 
• 116342-05-3 (3S,4R)-4-Chloro-1-oxa-spiro[2.5]octane 
• 591-49-1 1-methylcyclohex-1-ene 
• 1713-33-3 1,2-epoxy-1-methylcyclohexane 

Downstream Products

• 31171-59-2 N,N-dimethyl-1-cyclohexenylmethylamine 
• 583-60-8 2-Methylcyclohexanone 
• 72052-67-6 2-methylene-cyclohexylamine 
• 87555-89-3 magnesium chloride (1-cyclohexenyl)methylsulfinate 
• 101871-19-6 (2-cyclohex-1-enyl-ethyl)-methyl-amine 

Relevant academic research and scientific papers

Initiated tert-Butyl Hydroperoxide-loaded Low-temperature Autoxidation of Alkenes: Alternative Hydroperoxide Syntheses and the Preparation of a Complete Set of Reference Material

A complete set of characterization data for the allylic hydroperoxides prepared from 1-methylcyclohexene and the isomeric 4-methyloct-4-enes is presented.The data relies upon the preparation of allylic hydroperoxides by tert-butyl hydroperoxide-loaded autoxidations, singlet-ene oxidations and nucleophilic substitution reactions.Appropriate allylic alcohols and relevant scission products have been prepared to support the assignments given.

THE REACTION OF HYPOCHLOROUS ACID WITH OLEFINS. A CONVENIENT SYNTHESYS OF ALLYLIC CHLORIDES

The reaction of HOCl with more highly substituted olefins in methylene chloride affords allylic chlorides in 60-80percent isolated yields.The utility of the reaction is illustrated with the synthesis of Rose oxide and α-monoterpenes.