7154-56-5Relevant academic research and scientific papers
Synthesis and structure of group 4 symmetric amidinate complexes and their reactivity in the polymerization of α-olefins
Elkin, Tatyana,Kulkarni, Naveen V.,Tumanskii, Boris,Botoshansky, Mark,Shimon, Linda J. W.,Eisen, Moris S.
, p. 6337 - 6352 (2013/12/04)
The steric properties of various nitrogen substituents on amidines were tuned in order to obtain group 4 mono- and bis(amidinate) dimethylamido or chloride complexes. The amidinate dimethylamido and chloride complexes were prepared, and their solid-state
Catalytic and Non-catalytic Addition of Aromatic Amines to Terminal Acetylenes in the Presence of Mercury(II) Chloride and Acetate
Barluenga, Jose,Aznar, Fernando,Liz, Ramon,Rodes, Rosa
, p. 2732 - 2737 (2007/10/02)
The addition of aromatic amines to terminal acetylenes in the presence of catalytic amounts of mercury(II) chloride gives imines, enamines, and 1,2,3,4-tetrahydroquinoline derivatives; mercury(II) acetate shows considerably less catalytic activity and may be used for the non-catalytic preparation of imines, enamines, N,N'-disubstituted acetamidines, and N,N-disubstituted acetamides.
