71546-38-8

Basic information

• Product Name: 2-vinylcyclobutanone tosylhydrazone sodium salt
• Synonyms: 2-vinylcyclobutanone tosylhydrazone sodium salt
• CAS NO: 71546-38-8
• Molecular Weight: 286.33
• Mol File: 71546-38-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-vinylcyclobutanone tosylhydrazone sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: 2-vinylcyclobutanone tosylhydrazone sodium salt(71546-38-8)
• EPA Substance Registry System: 2-vinylcyclobutanone tosylhydrazone sodium salt(71546-38-8)

Safety Data

• Hazardous Substances Data: 71546-38-8(Hazardous Substances Data)

Upstream product

• 71546-40-2 2-Vinylcyclobutanon-4-methylphenylsulfonylhydrazon 

Downstream Products

• 58436-36-5 1-vinyl-1-cyclobutene 
• 80119-20-6 allylidenecyclopropane 
• 19995-92-7 1-Methylene-2-vinylcyclopropane 
• 4663-24-5 Propenylidencyclopropan 
• 96-39-9 methylcyclopentadiene 
• 930-26-7 3-methylene-1-cyclopentene 
• 71546-39-9 2-vinylcyclobutanone 

Relevant articles and documents

Carbene Rearrangements, X. 2-Vinylcyclobutylidene

The Bamford-Stevens reaction of 2-vinylcyclobutanone tosylhydrazone sodium salt (13) has been studied with respect to the potential carbene-carbene rearrangement 3 -> 4. 2-Vinylcyclobutylidene (3) surprisingly undergoes exlusively carbene rearrangements.In 3 the cyclobutylidene-methylenecyclopropane rearrangements to 16 and 17 dominate.The 1,3-carbon migration of the divalent carbon is not observed.