71639-41-3

Upstream product

• 112113-25-4 2-Phenyl-2-(phenyl-hydrazono)-acetamide 
• 112113-06-1 N-(Phenylglyoxyloyl)-1-piperidincarboximidoyl-(1-phenylhydrazid) 
• 104132-43-6 -N-(phenylglyoxyloyl)formimidoylchlorid 
• 104132-45-8 N-(Phenylglyoxyloyl)-1-piperidincarboximidoylchlorid 
• 104132-44-7 N-(Phenylglyoxyloyl)-1-pyrrolidincarboximidoylchlorid 
• 59-88-1 phenylhydrazine hydrochloride 
• 148637-95-0 (E)-2-Chloro-3-phenyl-3-phenylazo-acrylamide 
• 112113-04-9 -N-(phenylglyoxyloyl)formimidoyl-(1-phenylhydrazid) 
• 112113-05-0 N-(Phenylglyoxyloyl)-1-pyrrolidincarboximidoyl-(1-phenylhydrazid) 
• 154109-79-2 C₁₅H₁₁Cl₂N₃O 

Relevant academic research and scientific papers

1-Arylimino-pyrazole Betaines, Pyrazoles and 1,2,4-Triazines from 3-Arylazo-propenoic Acid N-Chloroamides

Reaction of 3-arylazo-propenoic acid amides 5 with NaOCl yields N-chloroamides 6 which give under alkaline conditions 1,2,4-triazines 9 and 10 (products of a Hofmann degradation).This reaction competes with an intramolecular electrophilic amination and a

RING TRANSFORMATIONS OF PYRAZOLONES VIA AZO-OLEFINS

Instead of substitution, 4-halo-pyrazolones undergo ring opening to azo-olefins (2, 12, 16) on reaction with nucleophiles.Attempted Hofmann degradation of N-Haloamides 4 has to compete with either ring closure, involving NHCl-shift to 7, or formation of m

Nucleophilic Reactions on Chloro-N-(2-oxoacyl)formamidines

Reaction of the chloroformamidines 1a-w with various O-, N-, and S-nucleophiles gives the substitution products 2a-h, 3a-d, 4a-g, 6a-g, 17a-c, and 21a-c or the heterocyclic compounds 7a-c, 8a-i, 9, 10, 11a-c, 12a-c, and 20a-j.The guanidines 4d, e are cycl