71660-50-9Relevant academic research and scientific papers
Reactions of Ruthenium Triphenylphosphine Complexes with Diazadienes. Part 1. Reactions of and and Disproportionation of a Hydridochloro-complex
Chaudret, Bruno,Poilblanc, Rene
, p. 539 - 544 (2007/10/02)
The reactions between and half or one equivalent of a diazadiene (dad) give respectively molecular and ionic binuclear triply chloro-bridged complexes, and Cl which can also be obtained as its BPh4 salt.The compound reacts with diazadienes to produce , which disproportionates in polar solvents to give a hydrido- and a dichloro-compound and reacts with water to give a chlorodihydroxo-bridged hydrido-species, .
