7169-14-4Relevant academic research and scientific papers
Helical aromatic oligoamides: Reliable, readily predictable folding from the combination of rigidified structural motifs
Yuan, Lihua,Zeng, Huaqiang,Yamato, Kazuhiro,Sanford, Adam R.,Feng, Wen,Atreya, Hanudatta S.,Sukumaran, Dinesh K.,Szyperski, Thomas,Gong, Bing
, p. 16528 - 16537 (2004)
Factors responsible for the folding of aromatic oligoamides with backbones rigidified by local three-center H-bonds were investigated. The stability of the three-center H-bonds was quantified by the half-lives of amide proton-deuterium exchange reactions,
Macrocyclic compound with hydrophobic inner cavity and preparation method of macrocyclic compound
-
Paragraph 0059; 0061-0063; 0066; 0068, (2020/08/29)
The invention discloses a macrocyclic compound with a hydrophobic inner cavity and a preparation method of the macrocyclic compound, and belongs to the technical field of light chemical engineering. The specific preparation method of the macrocyclic compo
Aromatic amides metal ligand capable of forming intramolecular hydrogen bond and preparation method and application thereof
-
Paragraph 0039; 0040; 0043; 0044, (2019/02/19)
The invention provides an aromatic amides metal ligand capable of forming an intramolecular hydrogen bond and a preparation method and application thereof, and belongs to the technical field of coordination polymer materials. In allusion to a problem in t
Compounds for use in treatment of mucostitis
-
Page/Page column 359, (2015/11/09)
The present invention provides methods for treating and/or preventing mucostitis with one or more compounds, or pharmaceutically acceptable salts thereof, disclosed herein, or compositions comprising the same.
Aromatic oligoamide macrocycles from the bimolecular coupling of folded oligomeric precursors
Yang, Liuqing,Zhong, Lijian,Yamato, Kazuhiro,Zhang, Xiaheng,Feng, Wen,Deng, Pengchi,Yuan, Lihua,Zeng, Xiao Cheng,Gong, Bing
supporting information; scheme or table, p. 729 - 733 (2009/06/20)
Aromatic oligoamide macrocycles consisting of six to ten meta-linked residues were prepared based on bimolecular coupling/cyclization of a pentameric diamine and oligomeric diacid chlorides, and adopt folded conformations enforced by intramolecular three-
Hydrogen-bonding-driven preorganized zinc porphyrin receptors for efficient complexation of C60, C70, and C60 derivatives
Wu, Zong-Quan,Shao, Xue-Bin,Li, Chuang,Hou, Jun-Li,Wang, Kui,Jiang, Xi-Kui,Li, Zhan-Ting
, p. 17460 - 17468 (2007/10/03)
This paper describes the self-assembly of a new class of foldamer-based molecular tweezers, whose rigid folded conformations are stabilized by intramolecular hydrogen bonding. Two zinc porphyrin units are introduced to the ends of molecular tweezers Zn21 and Zn22, while three zinc porphyrin units are incorporated to the S-shaped bi-tweezers Zn33, which may be regarded as a combination of two Zn21 molecules. Due to the preorganized U-shaped feature, Zn21 and Zn22 are able to strongly complex C60, C70, and C60 derivative 25 in chloroform or toluene in a 1:1 binding stoichiometry, whereas Zn33, which possesses two tweezer units, complexes the guests in a 1:2 stoichiometry. More stable complex Zn33·24 is formed between Zn33 and 24, a linear molecule bearing two C60 moieties at the ends, as a result of the cooperative interaction of two binding sites. Chiral induction is observed for all the three receptors upon complexation with C60-incorporated chiral phenylalanine derivative 29, although the complexation of 29 by the folding receptors is pronouncedly weaker than that of C60 and 25 due to increased steric hindrance. The driving force for the formation of the complexes is the well established π-π stacking between the zinc porphyrin and fullerene units. The 1H and 13C NMR, UV-vis, fluorescent, and circular dichroism spectroscopy have been used to investigate the complexing behavior of the folding receptors and the fullerene guests. The association constants of the corresponding complexes in toluene and chloroform (if possible) have been evaluated with the UV-vis and fluorescent titration experiments.
