71690-14-7

Upstream product

• 102845-00-1 N-(1-phenyl-3-methylbutyl)-2-aminodeoxybenzoin 
• 110222-12-3 2-[(E)-2-Methyl-1-phenyl-propylimino]-1,2-diphenyl-ethanone 
• 82022-20-6 N-(1-phenyl-2-methylpropyl)-2-aminodeoxybenzoin 
• 1689-71-0 2,3-diphenyloxirane 
• 6668-27-5 2-methyl-1-phenyl-propylamine 

Relevant academic research and scientific papers

STEREOCHEMISTRY OF IMINO-GROUP REDUCTION. PART 6. STEREOCHEMISTRY OF REDUCTION OF 1,2-IMINO KETONES HAVING A PRE-EXISTING CHIRAL CENTRE. SYNTHESIS OF AMINO ALCOHOLS WITH THREE CHIRAL CENTRES

Stereochemical results of the lithium aluminium hydride and sodium borohydride reduction of 1,2-imino ketones, PhCOCPh=NCHRPh (R = Me, Et, Pr, Bu, i-Bu, i-Pr, t-Bu), are reported.The stereoselectivity is accounted for by competition between two possible r

CONFIGURATIONAL ASSIGNMENT TO N-(1-PHENYLALKYL)-SUBSTITUTED 2-AMINO-1,2-DIPHENYLETHANOLS

Three-chiral centre aminoethanols are obtained by reduction of 1,2-imino ketones having a preexistenting chiral centre.Assignment of configuration to the aminoethanols has been carried out on the basis of high-dilution i.r., 1H n.m.r., and 13C n.m.r. spectroscopic data.