71706-88-2Relevant academic research and scientific papers
Concurrent Hydrogen Migration and Nitrogen Extrusion in the Excited States of Alkylchlorodiazirines
White, Walter R.,Platz, Matthew S.
, p. 2841 - 2846 (1992)
Laser flash photolysis of a series of alkylchlorodiazirines in the presence of pyridine generates easily detected, long-lived ylides.At large pyridine concentrations all of the alkylchlorocarbene generated in a laser flash is completely converted into ylide.The yield of ylide in this regime of pyridine concentration correlates with the α-C-H bond dissociation energy of the alkyl group.This demonstrates that hydrogen migration competes with carbene formation in the excited state of the precursor.
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrices
Wierlacher, Stefan,Sander, Wolfram,Uu, Michael T. H.
, p. 8943 - 8953 (2007/10/02)
Photolysis of 3-benzyl-3-chlorodiazirine and its deuterated homologues 3-chloro-3-(phenyldideuteriomethyl)diazirine and 3-chloro-3-((pentadeuteriophenyl)methyl)diazirine has been investigated by means of IR and UV-vis spectroscopy in argon and xenon matri
