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Carbamothioic acid, methylphenyl-, O-(4-methoxyphenyl) ester is a chemical compound with the molecular formula C15H17NO3S. It is an ester derivative of carbamothioic acid, featuring a methylphenyl group and a 4-methoxyphenyl group attached to the carbamothioic acid backbone. Carbamothioic acid, methylphenyl-, O-(4-methoxyphenyl) ester is known for its potential use as a pesticide or agrochemical, particularly as an insecticide. It works by inhibiting the activity of acetylcholinesterase, an enzyme that breaks down the neurotransmitter acetylcholine in the nervous system of insects. By blocking this enzyme, the compound leads to an accumulation of acetylcholine, which disrupts the normal functioning of the insect's nervous system, ultimately causing paralysis and death. The specific structure and properties of Carbamothioic acid, methylphenyl-, O-(4-methoxyphenyl) ester make it effective against a range of pests, highlighting its importance in agricultural applications for pest control.

7175-94-2

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7175-94-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7175-94-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,1,7 and 5 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 7175-94:
(6*7)+(5*1)+(4*7)+(3*5)+(2*9)+(1*4)=112
112 % 10 = 2
So 7175-94-2 is a valid CAS Registry Number.

7175-94-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name O-(4-methoxyphenyl) N-methyl-N-phenyl thiocarbamate

1.2 Other means of identification

Product number -
Other names O(4-methoxyphenyl)-N-methyl-N-phenyl thiocarbamate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7175-94-2 SDS

7175-94-2Relevant academic research and scientific papers

Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides

Baroudi, Abdulkader,Alicea, Jeremiah,Flack, Phillip,Kirincich, Jason,Alabugin, Igor V.

, p. 1521 - 1537 (2011/06/11)

We report a metal-free procedure for transformation of phenols into esters and amides of benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates, available in a single high-yielding step from phenols, selectively add silyl radicals at the sulfur atom of the CdS moiety. This addition step, analogous to the first step of the Barton-McCombie reaction, produces a carbon radical which undergoes 1,2 OfC transposition through an O-neophyl rearrangement. The usually unfavorable equilibrium in the reversible rearrangement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical, which furnishes the final benzoic ester or benzamide product. The metal-free preparation of benzoic acid derivatives from phenols provides a potentially useful alternative to metal-catalyzed carbonylation of aryl triflates.

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

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Page/Page column 15; 19, (2011/10/12)

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.

Metal-free transformation of phenols into substituted benzamides: A highly selective radical 1,2-O→C transposition in O-aryl-N-phenylthiocarbamates

Baroudi, Abdulkader,Flack, Phillip,Alabugin, Igor V.

supporting information; experimental part, p. 12316 - 12320 (2010/12/29)

Radical merry-go-round: A highly efficient metal-free transformation of phenols into benzamides is designed through one-step conversion of phenols to aryl thiocarbamates and a subsequent radical addition/rearrangement/ fragmentation cascade. Computational analysis fully rationalizes the experimentally observed selectivity. Despite the possible competition from N-C fragmentation and N-neophyl rearrangement, the transformation exclusively follows the most kinetically and thermodynamically favored O-neophyl rearrangement path.

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