718638-46-1Relevant academic research and scientific papers
Transmetalation of Alkylzirconocenes in Copper-Catalyzed Alkyl–Alkynyl Cross-Coupling Reactions
Indukuri, Kiran,Riant, Olivier
, p. 2425 - 2433 (2017/07/22)
A simple copper-catalyzed alkyl–alkynyl cross-coupling strategy has been developed using the reaction between alkynyl bromides and alkylzirconocenes. The alkylzirconocenes were generated in situ via regioselective addition of Schwartz's reagent (ZrCp2HCl) on to alkenes. The reaction has a broad scope, a range of functionalized bromoalkynes and alkylzirconium reagents were successfully coupled, resulting in moderate to good yields of the desired internal alkynes. (Figure presented.).
Hydrozirconation of first-generation allyl-functionalized dendrimers and dendrimer model compounds
Meijboom, Reinout,Moss, John R.,Hutton, Alan T.,Makaluza, Tracy-Ann,Mapolie, Selwyn F.,Waggie, Fazlin,Domingo, Mark R.
, p. 1876 - 1881 (2007/10/03)
Several allyl-functionalized dendrimers and mono-functional model compounds have been prepared. These have been hydrozirconated using [Cp2ZrHCl]x to give zirconocene terminated dendrimers. These dendrimers have been characterized usi
