71870-07-0Relevant academic research and scientific papers
PRIMARY AMINES VIA ELECTROPHILIC AMINATION OF ORGANOMETALLIC COMPOUNDS WITH O-(DIPHENYLPHOSPHINYL)HIDROXYLAMINE
Boche, Gernot,Bernheim, Michael,Schrott, Wolfgang
, p. 5399 - 5402 (1982)
It is shown that O-(diphenylphosphinyl)hydroxylamine 4a transforms all kinds of "carbanions" into primary amines; best yields are received with "stabilized anions", e.g. of the benzylic type.
Improved Reagent for Electrophilic Amination of Stabilized Carbanions
Smulik, Jason A.,Vedejs, Edwin
, p. 4187 - 4190 (2007/10/03)
(Equation presented) Enolate amination using O-di(p-methoxyphenyl) phosphinylhydroxylamine 2 is reported. Reagent 2 reacts efficiently with stabilized sodium or potassium enolates derived from malonates, phenylacetates, and phenylacetonitriles and is sufficiently soluble for use in solution at -78°C.
