71887-46-2Relevant academic research and scientific papers
Low Coordinated Phosphorous Compounds, 9. Pericyclic Reactions of Phospha-1,5-hexadiene Derivatives
Appel, Rolf,Barth, Volker,Halstenberg, Mechthild
, p. 1617 - 1625 (2007/10/02)
Reaction of phenylbis(trimethylsilyl)phosphane (1) with phenyl isocyanide dichloride (2a) yields two diastereomeric tetraphosphahexadienes 4a (rac- and meso-form). 31P NMR temperature-run shows identically -tetraphospha Cope rearrangement to the rac-form.The meso-form was isolated (X-ray datas). 1 reacts with succinyl dichloride to yield the diphospha-1,5-hexadiene 9, which undergoes spontanously -diphospha Cope rearrangement to the divinyldiphosphane 10.
(PHOSPHINOMETHYLEN)PHOSPHANE, 1,3,4,6-TETRAPHOSPHAHEXADIENE-(1,5) UND NEUE 1,3-DIPHOSPHETANE AUS R-N=CCl2 UND PhPTms2
Appel, Rolf,Laubach, Benno
, p. 2497 - 2500 (2007/10/02)
Interaction of different halogenated isocyanide dichlorides with phenylbis(trimethylsilyl)phosphine either yields 1,3,4,6-tetraphosphahexadienes-(1,5) via the (phosphinomethylene)phosphines or 1,3-diphosphetanes by way of the "monophosphacarbodiimides".
