71899-70-2

Basic information

• Product Name: 2-Butanone, 3-methyl-1-[(4-methylphenyl)sulfinyl]-, (R)-
• CAS NO: 71899-70-2
• Molecular Formula: C12H16O2S
• Molecular Weight: 224.324
• Mol File: 71899-70-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-methyl-1-[(4-methylphenyl)sulfinyl]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-methyl-1-[(4-methylphenyl)sulfinyl]-, (R)-(71899-70-2)
• EPA Substance Registry System: 2-Butanone, 3-methyl-1-[(4-methylphenyl)sulfinyl]-, (R)-(71899-70-2)

Safety Data

• Hazardous Substances Data: 71899-70-2(Hazardous Substances Data)

Upstream product

• 934-72-5 Methyl p-tolyl sulfoxide 
• 64480-03-1 (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl 2-methylpropanoate 
• 138522-73-3 1-(p-tolylthio)-3-methyl-2-butanone 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 97-62-1 Ethyl isobutyrate 

Downstream Products

• 62837-63-2 <2R,(S)R>-2,3-dimethyl-1-(4'-methylphenylsulfinyl)-2-butanol 
• 142076-02-6 (R)-2-Methyl-4-((R)-toluene-4-sulfinyl)-pentan-3-ol 
• 144782-51-4 (1R,(S)R)-N-benzyl-1-isopropyl-2-(p-tolylsulfinyl)ethylamine 
• 154582-10-2 (R)-2,3-dimethyl-1-(4'methylphenylthio)-2-butanol 
• 142075-92-1 (R_S)-2-methyl-4-<(4-methylphenyl)sulfinyl>pentan-3-one 
• 144782-47-8 Benzyl-[2-methyl-1-((R)-toluene-4-sulfinylmethyl)-prop-(E)-ylidene]-amine 

Relevant articles and documents

1,3-Asymmetric Induction in the Reduction of α-Alkyl β-Ketosulfoxides with DIBAL/ZnBr2

The highly stereoselective reduction of chiral α-alkyl β-ketosulfoxides with DIBAL/ZnBr2 is governed by the configuration at the sulfur (1,3-induction) and not by that of the C-α (1,2-induction) as it has been previously reported.This fact considerably in

The Preparation of Optically Active β-Keto Sulfoxides by Means of an Enantiomer-differentiating Reaction of α-Lithio Aryl Methyl Sulfoxides with Chiral Carboxylates

The reaction of α-lithio aryl methyl sulfoxides with a limited amount of chiral carboxylates (R2-CO-O-R*) was found to be an enantiomer-differentiating reaction, affording the corresponding optically active β-keto sulfoxides (3), tog