72018-83-8Relevant academic research and scientific papers
DERIVATE DES PHOSPHORSAEURE-o-PHENYLENESTERS. 20. Halogenierung von aromatischen o-Phenylenphosphiten. Ein Gleichgewicht zwischen Phosphonium- und Phosphoranstruktur
Gloede, Joerg,Gross, Hans,Michalski, Jan,Pakulski, Marek,Skowronska, Aleksandra
, p. 157 - 162 (2007/10/02)
The halogenation of phenyl- and o-methoxyphenyl-o-phenylene phosphites (1b,1c) gives at low temperature pentacoordinated dihalogenophosphoranes 4a, 4b, 5a, 5b.They are stable at room temperature with the exception of 5b.Even at -100 deg C 5b slowly gives a bromospirophosphorane 3b by breaking the ether linkage.The primary formed phosphorane is in an equilibrium with the phosphoniumsalt; both phosphorus compounds are proved with 31P n.m.r. spectroscopy.
