72024-49-8Relevant academic research and scientific papers
Electrosynthesis of: S -thiocarbamates with disulfides as a sulfur source
Liu, Xiaoying,Cai, Tian-Cheng,Guo, Dingyi,Nong, Zhibin,Yang, Yujie,Li, Qiang,Jiang, Hongmei,Liu, Xingru,Gui, Qing-Wen
supporting information, p. 657 - 660 (2022/01/22)
An electrochemical oxidative synthesis of S-thiocarbamates by a carbamothioation reaction via a three-component coupling reaction (disulfide, water and isocyanide) is developed, which avoids the use of external oxidants and generates only hydrogen gas as the by-product. With NH4I as the mediator and electrolyte, the desired S-thiocarbamates were obtained in good yields in an undivided cell at room temperature.
