72028-76-3

Downstream Products

• 115026-74-9 (3-Methyl-but-2-enoylamino)-phenyl-acetic acid benzyl ester 
• 218792-82-6 α-diazo-α-phenylacetic acid benzyl ester 
• 862453-52-9 Methylamino-phenyl-acetic acid benzyl ester 
• 193689-63-3 Phenyl-trifluoromethanesulfonylamino-acetic acid benzyl ester 
• 2392-54-3 (acetyl-methyl-amino)-phenyl-acetic acid 
• 200063-59-8 (Acetyl-methyl-amino)-phenyl-acetic acid benzyl ester 
• 193689-47-3 N-[2-(3,4-dimethoxyphenyl)ethyl]-N-trifluoromethanesulfonyl phenylglycine 
• 193689-59-7 {[2-(3,4-Dimethoxy-phenyl)-ethyl]-trifluoromethanesulfonyl-amino}-phenyl-acetic acid benzyl ester 
• 195719-43-8 [(2,2-Dimethyl-propionyl)-methyl-amino]-phenyl-acetic acid 
• 124901-22-0 C₅₁H₇₅NO₁₂ 
• 1234213-27-4 (S)-benzyl 2-((2S,5R,6R)-6-(1,3-dioxoisoindolin-2-yl)-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]-heptane-2-carboxamido)-2-phenylacetate 
• 1448155-27-8 C₆₃H₆₉N₇O₁₇S 
• 1448155-21-2 C₄₈H₅₈N₆O₁₆S 

Relevant academic research and scientific papers

O -Phthalaldehyde catalyzed hydrolysis of organophosphinic amides and other P(O)-NH containing compounds

Over 50 years ago, Jencks and Gilchrist showed that formaldehyde catalyses the hydrolysis of phosphoramidate through electrophilic activation, induced by covalent attachment to its nitrogen atom. Given our interest in the use of aldehydes as catalysts, this work was revisited to identify a superior catalyst, o-phthalaldehyde, which facilitates hydrolyses of various organophosphorus compounds bearing P(O)-NH subunits under mild conditions. Interestingly, chemoselective hydrolysis of the P(O)-N bonds could be accomplished in the presence of P(O)-OR bonds.

Study on synthesis, characteristics and catalysis properties of novel chiral metal complexes catalysts for 1,3-dipolar cycloaddition reactions of nitrone with electron-rich alkene

As a new class of potential catalysts for 1,3-dipolar cycloaddition reactions, fourteen L-amino acid Schiff base Cu(II) and Ti(IV) complexes were synthesized, characterized, and evaluated for their catalytic activities in the reaction between C, N-diphenylnitrone and electron-rich ethyl vinyl ether under both homogeneous and in situ conditions. The methods for preparation and utilization of the catalysts were elucidated in detail, and the results of the catalytic reactions were described and discussed as well. Excellent reaction results were found in the presence of some catalysts (20 mol%) with > 90% endo-isoazolidines produced, compared with predominantly exo-isoazolidine produced without a catalyst. In addition, the reaction rate is found to be enhanced remarkably by a Cu(II) complex Schiff base catalyst at room temperature.