72031-35-7Relevant articles and documents
Synthesis of Cyclooctatetraenes through a Palladium-Catalyzed Cascade Reaction
Blouin, Sarah,Gandon, Vincent,Blond, Ga?lle,Suffert, Jean
, p. 7208 - 7211 (2016)
Reported is a cascade reaction leading to fully substituted cyclooctatetraenes. This unexpected transformation likely proceeds through a unique 8π electrocyclization reaction of a ene triyne. DFT computations provide the mechanistic basis of this surprizing reaction.
A convenient and efficient preparation of β-substituted α-haloenones from diazodicarbonyl compounds
Lee, Yong Rok,Cho, Bang Sub,Kwon, Hyuk Jin
, p. 9333 - 9347 (2007/10/03)
Rhodium(II)-catalyzed reactions of cyclic diazodicarbonyl compounds with a variety of halides have been examined. With acid halides, β-acyloxy α-haloenones are produced in good yields. With benzyl halides, β-benzyloxy α-haloenones are obtained in good yie