72063-39-9

Basic information

• Product Name: spinosin
• Synonyms: spinosin;2-(4-Hydroxyphenyl)-5-hydroxy-7-methoxy-6-[2-O-(β-D-glucopyranosyl)-β-D-glucopyranosyl]-4H-1-benzopyran-4-one;2''-O-β-D-Glucopyranosylswertisin;6-(2-O-β-D-Glucopyranosyl-β-D-glucopyranosyl)-4',5-dihydroxy-7-methoxyflavone;6-(2-O-β-D-Glucopyranosyl-β-D-glucopyranosyl)-5-hydroxy-2-(4-hydroxyphenyl)-7-methoxy-4H-1-benzopyran-4-one;Spinosin A;6-(2-O-beta-D-Glucopyranosyl-beta-D-glucopyranosyl)-5-hydroxy-2-(4-hydroxyphenyl)-7-methoxy-4H-1-benzopyran-4-one;FlavoayaMenin
• CAS NO: 72063-39-9
• Molecular Formula: C28H32O15
• Molecular Weight: 608.546
• Product Categories: chemical reagent;pharmaceutical intermediate;phytochemical;reference standards from Chinese medicinal herbs (TCM).;standardized herbal extract
• Mol File: 72063-39-9.mol
• Article Data: 2

Chemical Properties

• Melting Point: 149 °C
• Boiling Point: 901.408 °C at 760 mmHg
• Flash Point: 296.669 °C
• Appearance: /
• Density: 1.72
• Vapor Pressure: 5.56E-35mmHg at 25°C
• Refractive Index: 1.733
• Storage Temp.: 2-8°C
• Solubility: DMSO (Slightly), Methanol (Slightly, Heated, Sonicated) Pyridine (Slightly)
• PKA: 5.71±0.40(Predicted)
• Stability: Hygroscopic
• CAS DataBase Reference: spinosin(CAS DataBase Reference)
• NIST Chemistry Reference: spinosin(72063-39-9)
• EPA Substance Registry System: spinosin(72063-39-9)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 72063-39-9(Hazardous Substances Data)

Usage

Uses

Spinosin is a C-glycoside flavonoid extracted from Zizhiphi Spinozae, improved pentobarbital-induced sleep.

Definition

ChEBI: A flavone C-glycoside that is flavone substituted by hydroxy groups at positions 5 and 4', a methoxy group at position 7 and a 2-O-beta-D-glucopyranosyl-beta-D /stereo>-glucopyranosyl residue at position 6 via a C-glycosidic linkage.

InChI:InChI=1/C28H32O15/c1-39-14-7-15-18(12(32)6-13(40-15)10-2-4-11(31)5-3-10)22(35)19(14)26-27(24(37)21(34)16(8-29)41-26)43-28-25(38)23(36)20(33)17(9-30)42-28/h2-7,16-17,20-21,23-31,33-38H,8-9H2,1H3/t16-,17-,20-,21-,23-,24-,25-,26+,27-,28+/m1/s1

Upstream product

• 1399718-57-0 6'''-(4'-O-β-D-glucopyranosyl)vanilloyl spinosin 

Downstream Products

• 60767-82-0 flavoayamenin nonamethyl ether 

Relevant articles and documents

Two new flavonoid glycosides from Semen Ziziphi Spinosae

Two novel flavonoid glycosides, 6-dihydrophaseoylspinosin (1) and 6,6-diferuloylspinosin (2), were isolated from the MeOH extract of Semen Ziziphi Spinosae, together with six known flavonoids, isovitexin-2-O-β-(6-O-E- feruloyl)glucopyranoside (3), spinosin (4), isospinosin (5), 6-feruloylspinosin (6), swertisin (7), and isovitexin-2-O-β-d-glucopyranoside (8). The structures of 1 and 2 were elucidated by spectroscopic methods including UV, IR, ESI-TOF-MS, 1D NMR, and 2D NMR experiments.