720709-34-2Relevant academic research and scientific papers
Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts
Jeong, Nakcheol,Kim, Dong Hoon,Choi, Jun Hun
, p. 1134 - 1135 (2007/10/03)
Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.
