7208-83-5Relevant academic research and scientific papers
Flash Photolysis Study of 3-Methylisoxazolopyridine
Donati, Donato,Ponticelli, Fabio,Bicchi, Paola,Meucci, Mario
, p. 5271 - 5274 (2007/10/02)
The photoreactivity of the title compound has been examined in MeOH, PriOH, MeCN, and MeCN/as-dimethylhydrazine solutions.A ketenimine and a spiroazirine intermediate account for the final products as well as for the transients observed in the flash photolysis experiments.It is also found that acid catalysis plays an important role in the reaction of spiroazirine to oxazolopyridine.
Photochemical rearrangements of 3-methyliscxazolopyridines
Donati, Donato,Fusi, Stefania,Ponticelli, Fabio,Tedeschi, Piero
, p. 1899 - 1905 (2007/10/02)
Irradiation in water-saturated ethyl ether of isoxazolopyridines 1a,e, beside the corresponding oxazolopyridines 2a,e, leads to N-methylcarboxamides 3a,e via 1-2 shift of the methyl group. The isoxazolopyridine 5, bearing a hydrazino group in 4-position, rearranges only to l-aminopyrazolopyridine 6.
