72081-04-0

Basic information

• Product Name: 4,7-Epoxyisobenzofuran-1(3H)-one, 3,3-dibutyl-3a,4,7,7a-tetrahydro-
• CAS NO: 72081-04-0
• Molecular Formula: C16H24O3
• Molecular Weight: 264.365
• Mol File: 72081-04-0.mol

Chemical Properties

• CAS DataBase Reference: 4,7-Epoxyisobenzofuran-1(3H)-one, 3,3-dibutyl-3a,4,7,7a-tetrahydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 4,7-Epoxyisobenzofuran-1(3H)-one, 3,3-dibutyl-3a,4,7,7a-tetrahydro-(72081-04-0)
• EPA Substance Registry System: 4,7-Epoxyisobenzofuran-1(3H)-one, 3,3-dibutyl-3a,4,7,7a-tetrahydro-(72081-04-0)

Safety Data

• Hazardous Substances Data: 72081-04-0(Hazardous Substances Data)

Upstream product

• 6118-51-0 exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 
• 693-03-8 n-butyl magnesium bromide 

Relevant articles and documents

ETUDE DE L'ACTION DES ALKYLMAGNESIENS PRIMAIRES ET ARYLMAGNESIENS SUR LES ANHYDRIDES TRICYCLIQUES PONTES

The reaction of primary alkyl and aromatic Grignard reagents with bridged tricyclic dicarboxylic anhydrides gives the corresponding dialkylated tricyclic lactones via di-addition process.The lactones were transformed by retro-Diels-Alder reaction into 4,4-dialkylated butenolides.

A FACILE AND GENERAL ROUTE TO 4-SUBSTITUTED-2 BUTENOLIDES

Grignar reagents react with 7-oxabicyclohept-5-ene-2,3-dicarboxylic anhydride and produce in high yields the corresponding substituted bicyclo-γ-butanolides.These lactones produce the title compounds by retro Diels-Alder reaction during distillation.